Mechanism of capture of ionic impurities from electrolytes, based on a bipolar cell of oscillating porous electrodes, spaced by the equilibrium distances
نویسندگان
چکیده
This work proposes the use of electrochemical cells (bipolar or series) like mechanism recuperate of impurities and noble species, from contaminated or impoverished electrolytes. The treated fluid circulates through porous or perforated electrodes of compound material. In order to produce successive, selective deposits of the different chemical substances, these electrodes are located spaced by specific distances. Different prototypes of electrodes were elaborated starting from a conductive base material with small dielectric zones, which can have their origin in ceramic particles or pores. The rate and selectivity of capture was related to the porosity and nature of the base of the electrode, quantified by the size, geometry, average density and distribution of the dielectric zones in the conductive matrix of the electrode. The longitudinal coordinates of each electrode are determined by means of the plainer of the electric field, which appears between the terminal electrodes, anode and cathode, polarized by an external source of tension. Using methods of finite mathematics the map of the equipotential lines was simulated and the location exact of each electrode so that by effect of his polarization it extracts a single chemical species was found. The type and the number of electrodes of the cell filter are determined by the time of residence required by the fluid to process, in order to obtain an appropriate deposit based on the volumetric flow, the composition and concentration of impurities and noble species.
منابع مشابه
STRUCTURAL AND IONIC CONDUCTIVITYSTUDIES ONPLASTICIZED PAN-SODIUM FLUORIDE POLYMER ELECTROLYTES FOR ELECTROCHEMICAL CELL APPLICATIONS
Ion conducting gel polymer electrolytes based on poly acrylonitrle (PAN) complexed with different weight percent ratios of Sodium Fluoride (NaF) salt were prepared by using solution cast technique. Structural characterization was performed using X-ray diffraction (XRD) technique and Fourier transforms infrared (FTIR) spectroscope technique. From the X-rd results increase in amorphous phase with...
متن کاملRemoval of Basic Dye Bromophenol Blue from aqueous solution by Electrocoagulation using Al – Fe Electrodes: Kinetics, Equilibrium and Thermodynamics Studies.
Electrocoagulation (EC) in a batch cell with Al anode and Fe cathode in monopolar parallel (MP) connection was used for the removal of basic dye, Bromophenol Blue (BPB). The effects of current density, pH, temperature and initial dye concentration, on the process were investigated. Equlibrium data were analyzed using four model equations: Langmuir, Freudlinch, Temkin and Dubinin–Radushkevich. D...
متن کاملVapor-Pressure Osmometry and Conductivity Determination of Salting-Out Effects in Aqueous Surface-Active Ionic Liquid 1-Dodecyl-3-methylimidazolium Bromide Solutions
Systematic studies on the vapor-liquid equilibria (VLE) and conductometric properties of aqueous solutions of model surface-active ionic liquid 1-dodecyl-3-methylimidazolium bromide ([C12mim]Br) are performed in the absence and presence of a large series of electrolytes in order to achieve a deeper understanding about the molecular mechanism behind the specific salt effect on the aggregation be...
متن کاملSecond Law Based Analysis of Fluid Flow in the Regenerator of Pulse Tube Refrigerators
As a necessary component, regenerator plays an important role in the refrigeration performance of the pulse tube refrigerator. The objective of this research is to investigate the flow characteristics in a porous regenerator of the pulse tube refrigerators, subjected to oscillating flow. The hydrodynamic and thermal behavior of the regenerator is investigated by considering porous media approac...
متن کاملImpact of anisotropy level of gas diffusion layer on the temperature distribution of a PEM fuel cell cathode electrode
Proton exchange membrane (PEM) fuel cells being employed in fuel cell vehicles (FCVs) are promising power generators producing electric power from fuel stream via porous electrodes. Structure of carbon paper gas diffusion layers (GDLs) applying in the porous electrodes can have a great influence on the PEM fuel cell performance and distribution of temperature, especially at the cathode side whe...
متن کامل